Surface Electron Dynamics for Intercalated Graphene (and Other 2D Materials) on a Metal Template

In this dissertation, I report my thesis work on studying surface electron dynamics for intercalated graphene on a metal template using both experimental and theoretical methods. A general description of the research motivation is summarized in the first Chapter. The experimental and theoretical techniques involved in this thesis research are introduced in Chapter 2. In Chapter 3 and Chapter 4, the key findings of this thesis work are reported. These findings concern two novel surface electronic phenomena in oxygen intercalated-graphene on Ir(111) interface. The first phenomenon was the observation of strongly excited image potential states (IPS) in a well-defined quasi-free-standing graphene (QFG) at an oxygen-intercalated Gr/Ir interface. Specifically, the interfaces were synthesized to form Gr/Ir and QFG (Gr/O/Ir) by oxygen intercalation. The syntheses were monitored by low-energy-electron-diffraction (LEED). Our research succeeded in exciting and measuring IPSs on both interfaces by angle-resolved two-photon-photoemission (AR-2PPE) and then the increasing of the IPS binding energy of 0.17 eV following the oxygen intercalation. Finally, our work proposed a theoretical model base